A comparison of chemical mechanisms based on TRAMP-2006 field data

A comparison of a model using five widely known mechanisms (RACM, CB05, LaRC, SAPRC-99, SAPRC-07, and MCMv3.1) has been conducted based on the TexAQS II Radical and Aerosol Measurement Project (TRAMP-2006) field data in 2006. The concentrations of hydroxyl (OH) and hydroperoxy (HO₂) radicals were calculated by a zero-dimensional box model with each mechanism and then compared with the OH and HO₂ measurements. The OH and HO₂ calculated by the model with different mechanisms show similarities and differences with each other and with the measurements. First, measured OH and HO₂ are generally greater than modeled for all mechanisms, with the median modeled-to-measured ratios ranging from about 0.8 (CB05) to about 0.6 (SAPRC-99). These differences indicate that either measurement errors, the effects of unmeasured species or chemistry errors in the model or the mechanisms, with some errors being independent of the mechanism used. Second, the modeled and measured ratios of HO₂/OH agree when NO is about 1 ppbv, but the modeled ratio is too high when NO was less and too low when NO is more, as seen in previous studies. Third, mechanism–mechanism HO_x differences are sensitive to the environmental conditions – in more polluted conditions, the mechanism–mechanism differences are less. This result suggests that, in polluted conditions, the mechanistic details are less important than in cleaner conditions, probably because of the dominance of reactive nitrogen chemistry under polluted conditions.     

A new metric space incorporating radon-222 for generation of back trajectory clusters in atmospheric pollution studies

A novel metric space for the clustering of back trajectories to be used in fine particle aerosol data analysis was proposed and evaluated. The metric is based on spatial and non-spatial variables incorporating great-circle distance, altitude and radon-222.Its performance was examined using the intra-cluster variation of measured and fingerprint apportioned aerosol mass as the quantitative criterion. The new metric was demonstrated to perform better than those based on great-circle distance, or a great-circle distance and altitude alone. The same criterion was applied to investigate the clustering performance as a function of the length of its back trajectories. The optimum back trajectory length was found to be dependent on the pollution source being considered.Performance tests, as well as the application of the new metric space to re-analysis of previously published results, were based on a three year long dataset comprising co-located aerosol fine particles (PM_2.5) collection and hourly measurements of radon-222 concentration.The new metric space can easily be redefined to include other trace species.     

What drives plan implementation? Plans,planning agencies and developers

This article investigates the determinants of plan implementation by applying a recently‐developed Plan Implementation Evaluation methodology. The lack of methodology to assess the implementation of plans has so far precluded any systematic analysis of the determinants of the implementation of local environmental plans. The article focuses on the implementation of plans in New Zealand. The key factors of implementation are: the quality of the plan; the capacity and commitment of land developers to implement plans; the capacity and commitment of the staff and leadership of planning agencies to implement plans; and the interactions between developers and the agency. The analysis is based on 353 permits implementing six local environmental plans in New Zealand, and on surveys of the developers who obtained the permits and of the planning agencies that granted the permits. The analysis finds that plan implementation is mainly driven by the resources of the planning agencies and by the quality of the plans, rather than by the characteristics of developers. Investments in plan writing and agency and staff capacity building thus improve the implementation of plans in the long‐run.     

Biochemical and ecological similarities in marsh plants and diving animals

Higher plants which can survive flooding have certain ecological and biochemical similarities with diving reptiles, birds, and mammals. The ecological similarities arise from the fact that these wet-land plants and diving animals are all terrestrial organisms which have re-entered the aquatic habitat as a retreat or ecological refuge free from interference by dry-land species. To survive in the wet-land or aquatic habitat species of terrestrial origin have to restrict their metabolic rate in the absence of oxygen and exploit a wide range of metabolic products to aid proton disposal and avoid the dangers of cell toxicity due to the accumulation of an excessive oxygen debt. In some plants metabolic adaptation to anoxia (low oxygen supply) resembles that found in animal parasites. It is a striking example of metabolic co-evolution that the retreat of so many terrestrial species of both plants and animals back to the low-oxygen habitat has been made possible by the exploitation of similar biochemical control mechanisms and pathways.     

Climate change and human health—what influences the adoption of adaptation programming in the United States public health system?

With growing evidence on how climate change impacts human health, public health agencies should develop adaptation programs focused on the impacts predicted to affect their jurisdictions. However, recent research indicates that public health agencies in the United States have done little to prepare the public for predicted climate change impacts, largely due in response to a lack of resources and priority. This study surveyed Environmental Health (EH) Directors across the United States to determine the extent to which individual level attitudes and beliefs influence the adoption of climate change adaptation programming in a department. The results indicate that an EH Director’s perception of the health risk posed by climate change explained 27% of the variance in the number of climate change impacts being addressed. Furthermore, the study found that environmental attitude and political views made strong, unique contributions in explaining the variance in risk perception. The results provide evidence that individual-level attitudes and beliefs, as well as organizational-level barriers influence the adoption of climate change adaptation programs in public health agencies. As a result, increasing EH Directors’ perception of risk by highlighting the likelihood and severity of localized impacts may increase the adoption of adaptation programming despite existing organizational barriers (e.g., lack of resources). Given the fact that risk perception has been shown to influence behavior across cultures, these findings are also useful for understanding the influence of individual decision makers on public health programming around the world.     

The effects of feeding by the black bean aphidAphis fabae Scop. (Homoptera: Aphididae) on copper and cadmium accumulation in broad bean (Vicia faba L.)

Broad beans (Vicia faba L.), cultured hydroponically were supplied with 100 g mL^–1 copper or 50 g mL^–1 cadmium in nutrient solution. Samples of plant material from both nutrient regimes were analysed before and after infestation by the black bean aphid (Aphis fabae Scop.). Heavy aphid infestation resulted in a significant reduction in copper content of shoots in comparison with uninfested plants. A similar, but less well- defined, situation occurred in the case of cadmium.Further investigations examined the effects of different levels of aphid infestation on the above phenomena. In all cases the presence of feeding aphids reduced elemental accumulation in plant shoots. Long term infestation with population densities as low as three adult aphids showed a reduction in shoot copper and cadmium content.     

Defining ecologically relevant scales for spatial protection with long‐term data on an endangered seabird and local prey availability

Human activities are important drivers of marine ecosystem functioning. However, separating the synergistic effects of fishing and environmental variability on the prey base of nontarget predators is difficult, often because prey availability estimates on appropriate scales are lacking. Understanding how prey abundance at different spatial scales links to population change can help integrate the needs of nontarget predators into fisheries management by defining ecologically relevant areas for spatial protection. We investigated the local population response (number of breeders) of the Bank Cormorant (Phalacrocorax neglectus), a range‐restricted endangered seabird, to the availability of its prey, the heavily fished west coast rock lobster (Jasus lalandii). Using Bayesian state‐space modeled cormorant counts at 3 colonies, 22 years of fisheries‐independent data on local lobster abundance, and generalized additive modeling, we determined the spatial scale pertinent to these relationships in areas with different lobster availability. Cormorant numbers responded positively to lobster availability in the regions with intermediate and high abundance but not where regime shifts and fishing pressure had depleted lobster stocks. The relationships were strongest when lobsters 20–30 km offshore of the colony were considered, a distance greater than the Bank Cormorant's foraging range when breeding, and may have been influenced by prey availability for nonbreeding birds, prey switching, or prey ecology. Our results highlight the importance of considering the scale of ecological relationships in marine spatial planning and suggest that designing spatial protection around focal species can benefit marine predators across their full life cycle. We propose the precautionary implementation of small‐scale marine protected areas, followed by robust assessment and adaptive‐management, to confirm population‐level benefits for the cormorants, their prey, and the wider ecosystem, without negative impacts on local fisheries.     

Sustainability in the USA and New Zealand: explaining and addressing the implementation gap in local government

This paper describes the frustrating reality of sustainability implementation in the USA and New Zealand (NZ), an early adopter of sustainability mandates. Local government has a key role in implementation, but has been slow to uptake sustainable practices. We surveyed senior planners in small to medium-sized local government agencies in both countries to identify which features of local government support (or hinder) sustainability in practice.

Environmentally sustainable practices are not well entrenched in either country. In the USA, the framing of sustainability and public support are significant predictors of implementation. However, sustainability is rarely a priority. In NZ, local government capacity is the main driver of implementation. We recommend that planners promote sustainability values, reconcile economic development goals with sustainability (e.g., green economy model), and translate public support for sustainability into institutional priorities. NZ localities also need increased capacity and US localities need continued Federal and State support.     

Use of three monitoring approaches to manage a major <Emphasis Type="Italic">Chrysosporum ovalisporum</Emphasis> bloom in the Murray River,Australia, 2016

An unusual bloom of Chrysosporum ovalisporum (basionym Aphanizomenon ovalisporum) occurred for the first time in the Murray River and distributary rivers in New South Wales, Australia, from mid-February to early June 2016. At its greatest extent, it contaminated a combined river length of ca. 2360 km. Chrysosporum ovalisporum usually comprised >99% of the total bloom biovolume at most locations sampled, which at times exceeded 40 mm³ l^?1. The origins of the bloom were most likely reservoirs on the upper Murray River, with cyanobacterial-infested water released from them contaminating the river systems downstream. An integrated approach using three analytical methods: (1) identification and enumeration by microscopy, (2) multiplex quantitative polymerase chain reaction (qPCR), and (3) toxin analysis, was used to obtain data for the assessment of risk to water users and management of the bloom. qPCR indicated some cyrA and stxA genes responsible for cylindrospermopsin and saxitoxin biosynthesis respectively were present, but mostly below the level of quantification. No mcyE genes for microcystin biosynthesis were detected. Toxin analysis also revealed that cylindrospermopsin, saxitoxin and microcystin were all below detection. Lack of measurable toxicity in a species usually considered a cylindrospermopsin producer elsewhere meant the possibility of relaxing management guidelines; however, high (Red) alerts needed to be maintained due to risk to water users from other biohazards potentially produced by the cyanobacteria such as contact irritants. A three-tiered monitoring strategy is suggested for monitoring cyanobacterial blooms to provide enhanced data for bloom management.